(2,2′-Bipyridine-κ2 N,N′)bis­(3-meth­oxy­benzoato-κ2 O 1,O 1′)copper(II) mono­hydrate

نویسندگان

  • Ming-Hao Lin
  • Jing-Fan Zhou
  • Bin-Bin Liu
  • Jian-Li Lin
چکیده

The title compound, [Cu(C(8)H(7)O(3))(2)(C(10)H(8)N(2))]·H(2)O, is comprised of a Cu(II) ion, two 3-meth-oxy-benzoate ligands, a 2,2'-bipyridine (bipy) ligand and one uncoordinated water mol-ecule. The Cu(II) ion and the water O atom lie on a twofold axis. The Cu(II) ion exhibits a six-coordinate distorted octa-hedral geometry, with two N atoms from the bipy ligand [Cu-N = 1.9996 (16) Å] and four O atoms from two 3-meth-oxy-benzoate ligands [Cu-O = 1.9551 (15) and 2.6016 (16) Å]. The mol-ecules are linked by O-H⋯O and C-H⋯O hydrogen bonds, forming a three-dimensional network.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Bis(μ-3-nitro­phthalato-κ2 O 1:O 2)bis­[aqua­(2,2′-bipyridine-κ2 N,N′)copper(II)] dihydrate

Two 3-nitro-phthalate dianions bridge two water-coordinated 2,2'-bipyridine-chelated Cu(II) atoms about a center of inversion to generate the title dinuclear compound, [Cu(2)(C(8)H(3)NO(6))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O. The geometry of the Cu(II) atom is a distorted square pyramid. Adjacent mol-ecules are linked through the coordinated and solvent water mol-ecules to form a linear rib...

متن کامل

Diammonium bis­[(2-amino­acetato-κ2 N,O)(2,2′-bipyridine-κ2 N,N′)(N,N-dimethyl­formamide-κO)copper(II)] hexa­cosa­oxidoocta­molybdate(VI)

The title compound, (NH(4))(2)[Cu(C(2)H(4)NO(2))(C(10)H(8)N(2))(C(3)H(7)NO)](2)[Mo(8)O(26)], contains a centrosymmetric β-type octa-molybdate anion, two copper(II) complex cations and two ammonium ions. The Cu(II) atom is coordinated in a square-pyramidal geometry by a 2,2'-bipyridine and a 2-amino-acetate ligands in the basal plane and by an O atom of N,N-dimethyl-formamide in the apical posit...

متن کامل

(μ-5-Carboxy­benzene-1,3-dicarboxyl­ato-κ2 O 1:O 3)bis­[bis­(2,2′-bipyridine-κ2 N,N′)copper(II)] 5-carboxy­benzene-1,3-dicarboxyl­ate 2,2′-bipyridine solvate trideca­hydrate

The asymmetric unit of the title complex, [Cu(2)(C(9)H(4)O(6))(C(10)H(8)N(2))(4)](C(9)H(4)O(6))·C(10)H(8)N(2)·13H(2)O, comprises two formula units. The two Cu(II) centres are bridged by a 5-carb-oxy-benzene-1,3-dicarboxyl-ate (Hbtc) ligand. Each of the metal centres is bonded to four N atoms of two bidentate 2,2'-bipyridine ligands (bpy) and one O atom of the Hbtc ligand in a highly distorted s...

متن کامل

(2,2′-Bipyridine-κ2 N,N′)bis­(4-hydroxy­benzoato-κ2 O,O′)lead(II) monohydrate

The reaction of lead acetate, 4-hydroxy-benzoic acid and 2,2'-bipyridine in aqueous solution gave the title complex, [Pb(C(7)H(5)O(3))(2)(C(10)H(8)N(2))]·H(2)O. The asymmetric unit contains one Pb(II) atom, two 4-hydroxy-benzoate ligands, one 2,2'-bipyridine ligand and one uncoordinated water mol-ecule. The Pb(II) atom is hexa-coordinated in a distorted tetra-gonal-bipyramidal geometry and is c...

متن کامل

(4,4′-Di-tert-butyl-2,2′-bipyridine-κ2 N,N′)bis­(nitrato-κ2 O,O′)copper(II)

In the crystal of the title compound, [Cu(NO(3))(2)(C(18)H(24)N(2))], the Cu(II) ion is coordinated by two N atoms of the bipyridine ligand and four O atoms from the two nitrate anions in a distorted octahedral fashion. The dihedral angle between the planes of the two pyridine rings is 11.52 (10)°. In the crystal structure, weak C-H⋯O inter-actions may help to establish the packing.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2011